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Ralf's Chat is a simple, easy to install and easy to configure chat script written in Perl. Features: language files, user levels, multiple rooms, session IDs, a DBI for MySQL (optional), streaming (requires MySQL) and a lot more.
Price: GPL

VChat is a real-time chat system that features: Private instant messages (like AOL), Private rooms, Unlimited rooms, User rooms, Users can kick others out of their own rooms, Users can give their room a topic, Users can send others instant sounds, Users can send instant pictures to each other, Send instant files to anyone, Send an instant page to anyone, Send auto invite-to-room window to anyone, Global profile database, Banner system, An automated buddylist, Real-time userslist for each room, Automated network chat bot, Network bot can auto-kick any user off the network after a number of offences, Network bot supports automated chat censor, Automated news broadcasting system, Users can chat with differnt colors and different fonts, Network supports automated file clean-up, Admin can ban anyone instantly, Admin can create public rooms instantly and much more.
Price: $299.99

WebChat is a useful application that allows a number of people on the World Wide Web to talk to one another simultaneously. The ability to chat on the Web can be a quick way to hold a virtual meeting.
Price: Freeware

WebChatter utilizes server push technology to achieve a realtime chat environment. Features include unlimited public and private rooms, op, kick, ban, live web page chat, news feeds, games, and more. This is the actual Perl source code to WebChatter.
Price: $499.95/Free for Members